Designing photochemical molecular devices utilizing Os and Ru polyazine light absorbers and Rh and Pt reactive sites: Applications in solar energy conversion and photodynamic therapy

Karen J. Brewer; Mark Elvington; Ran Miao; Matthew T. Mongelli; Jerita Dubash; Matthew Jeletic; Julie Heinecke

Designing photochemical molecular devices utilizing Os and Ru polyazine light absorbers and Rh and Pt reactive sites: Applications in solar energy conversion and photodynamic therapy

Karen J. Brewer, Mark Elvington, Ran Miao, Matthew T. Mongelli, Jerita Dubash, Matthew Jeletic, Julie Heinecke

Chemistry

Virginia Polytechnic Institute and State University

Research output: Contribution to journal › Conference article › peer-review

Abstract

Mixed-metal supramolecular complexes are a promising structural motif for the construction of a wide assortment of photochemical molecular devices. Coupling of Ru or Os light absorbers to Rh or Pt reactive centers yields complexes that display an array of interesting photochemical properties. Through modification of the components used in these devices, systems that function as photoinitiated electron collection devices, photocatalysts for the production of hydrogen from water, new types of photodynamic therapy agents and chromophoric DNA binding agents, are produced. Factors impacting the selection of device components and aspects of the photochemical reactivity of these complexes are presented. This is an abstract of a paper presented at the 229th ACS National Meeting (San Diego, CA 3/13-17/2005).

Original language	English
Pages (from-to)	INOR-410
Journal	ACS National Meeting Book of Abstracts
Volume	229
Issue number	1
State	Published - 2005
Event	229th ACS National Meeting - San Diego, CA., United States Duration: 13 Mar 2005 → 17 Mar 2005

Cite this

@article{da65e012fbf24408bddd66dcff2d181d,

title = "Designing photochemical molecular devices utilizing Os and Ru polyazine light absorbers and Rh and Pt reactive sites: Applications in solar energy conversion and photodynamic therapy",

abstract = "Mixed-metal supramolecular complexes are a promising structural motif for the construction of a wide assortment of photochemical molecular devices. Coupling of Ru or Os light absorbers to Rh or Pt reactive centers yields complexes that display an array of interesting photochemical properties. Through modification of the components used in these devices, systems that function as photoinitiated electron collection devices, photocatalysts for the production of hydrogen from water, new types of photodynamic therapy agents and chromophoric DNA binding agents, are produced. Factors impacting the selection of device components and aspects of the photochemical reactivity of these complexes are presented. This is an abstract of a paper presented at the 229th ACS National Meeting (San Diego, CA 3/13-17/2005).",

author = "Brewer, {Karen J.} and Mark Elvington and Ran Miao and Mongelli, {Matthew T.} and Jerita Dubash and Matthew Jeletic and Julie Heinecke",

year = "2005",

language = "English",

volume = "229",

pages = "INOR--410",

journal = "ACS National Meeting Book of Abstracts",

issn = "0065-7727",

publisher = "American Chemical Society",

number = "1",

note = "229th ACS National Meeting ; Conference date: 13-03-2005 Through 17-03-2005",

}

Designing photochemical molecular devices utilizing Os and Ru polyazine light absorbers and Rh and Pt reactive sites: Applications in solar energy conversion and photodynamic therapy. / Brewer, Karen J.; Elvington, Mark; Miao, Ran et al.
In: ACS National Meeting Book of Abstracts, Vol. 229, No. 1, 2005, p. INOR-410.

Research output: Contribution to journal › Conference article › peer-review

TY - JOUR

T1 - Designing photochemical molecular devices utilizing Os and Ru polyazine light absorbers and Rh and Pt reactive sites

T2 - 229th ACS National Meeting

AU - Brewer, Karen J.

AU - Elvington, Mark

AU - Miao, Ran

AU - Mongelli, Matthew T.

AU - Dubash, Jerita

AU - Jeletic, Matthew

AU - Heinecke, Julie

PY - 2005

Y1 - 2005

N2 - Mixed-metal supramolecular complexes are a promising structural motif for the construction of a wide assortment of photochemical molecular devices. Coupling of Ru or Os light absorbers to Rh or Pt reactive centers yields complexes that display an array of interesting photochemical properties. Through modification of the components used in these devices, systems that function as photoinitiated electron collection devices, photocatalysts for the production of hydrogen from water, new types of photodynamic therapy agents and chromophoric DNA binding agents, are produced. Factors impacting the selection of device components and aspects of the photochemical reactivity of these complexes are presented. This is an abstract of a paper presented at the 229th ACS National Meeting (San Diego, CA 3/13-17/2005).

AB - Mixed-metal supramolecular complexes are a promising structural motif for the construction of a wide assortment of photochemical molecular devices. Coupling of Ru or Os light absorbers to Rh or Pt reactive centers yields complexes that display an array of interesting photochemical properties. Through modification of the components used in these devices, systems that function as photoinitiated electron collection devices, photocatalysts for the production of hydrogen from water, new types of photodynamic therapy agents and chromophoric DNA binding agents, are produced. Factors impacting the selection of device components and aspects of the photochemical reactivity of these complexes are presented. This is an abstract of a paper presented at the 229th ACS National Meeting (San Diego, CA 3/13-17/2005).

UR - http://www.scopus.com/inward/record.url?scp=22744452785&partnerID=8YFLogxK

M3 - Conference article

AN - SCOPUS:22744452785

SN - 0065-7727

VL - 229

SP - INOR-410

JO - ACS National Meeting Book of Abstracts

JF - ACS National Meeting Book of Abstracts

IS - 1

Y2 - 13 March 2005 through 17 March 2005

ER -

Designing photochemical molecular devices utilizing Os and Ru polyazine light absorbers and Rh and Pt reactive sites: Applications in solar energy conversion and photodynamic therapy

Abstract

Other files and links

Fingerprint

Cite this